Magnetic instabilities in Fe3C cementite particles observed with Fe K-edge x-ray circular dichroism under pressure.

نویسندگان

  • E Duman
  • M Acet
  • E F Wassermann
  • J P Itié
  • F Baudelet
  • O Mathon
  • S Pascarelli
چکیده

The ferromagnetic interstitial iron compound Fe(3)C (cementite) is expected to have Invar properties, whereby a high-moment to low-moment transition should occur when the atomic volume is reduced below a critical value. We, therefore, examine the pressure dependence of the Fe K-edge x-ray magnetic circular dichroism in Fe(3)C at ambient temperature and pressures up to 20 GPa. We find clear evidence for a high-moment to low-moment transition around 10 GPa.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

XMCD under pressure at the Fe K edge on the energy-dispersive beamline of the ESRF.

The present paper demonstrates the feasibility of X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD) at high pressure at the Fe K edge on the ID24 energy-dispersive beamline of the ESRF. In 3d transition metals, performing experiments at the hard X-ray K edge rather than at the magnetically interesting soft X-ray L edges represents the only way to access the high-p...

متن کامل

Multi-frame acquisition scheme for efficient energy-dispersive X-ray magnetic circular dichroism in pulsed high magnetic fields at the Fe K-edge

Using a fast silicon strip detector, a multi-frame acquisition scheme was implemented to perform energy-dispersive X-ray magnetic circular dichroism at the iron K-edge in pulsed high magnetic fields. The acquisition scheme makes use of the entire field pulse. The quality of the signal obtained from samples of ferrimagnetic erbium iron garnet allows for quantitative evaluation of the signal ampl...

متن کامل

Magnetic Small Angle X-Ray Scattering

We present first experimental results of the extension of X-ray Magnetic Circular Dichroism (X-MCD) to Small Angle X-ray Scattering (SAXS). The purpose of this study is to determine size distributions and correlations lengths in the nanometer range of magnetic precipitates in granular systems. Magnetic scattering curves obtained with a GdFe system at the Gd La edge are compared with reference m...

متن کامل

Electronic and magnetic structure of C60/Fe3O4(001): a hybrid interface for organic spintronics

We report on the electronic and magnetic characterization of the hybrid interface constituted of C60 molecules and an epitaxial Fe3O4(001) surface grown on GaAs(001). Using X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD), we demonstrate that a stable C60 sub-monolayer (ML) can be retained on the Fe3O4(001) surface upon in situ annealing at 250 C. A carbon K-edge...

متن کامل

Pressure-induced magnetic switching and linkage isomerism in K0.4Fe4[Cr(CN)6]2.8 x 16 H2O: X-ray absorption and magnetic circular dichroism studies.

The effect of applied pressure on the magnetic properties of the Prussian blue analogue K0.4Fe4[Cr(CN)6]2.8 x 16 H2O (1) has been analyzed by dc and ac magnetic susceptibility measurements. Under ambient conditions, 1 orders ferromagnetically at a critical temperature (T(C)) of 18.5 K. Under application of pressure in the 0-1200 MPa range, the magnetization of the material decreases and its cri...

متن کامل

ذخیره در منابع من

ذخیره در منابع من قبلا به منابع من ذحیره شده

{@ msg_add @}


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Physical review letters

دوره 94 7  شماره 

صفحات  -

تاریخ انتشار 2005